{Bis[2-(diphenylphosphanyl)phenyl] ether-κ2 P,P′}(1,1′-dibenzyl-1H,1′H-4,4′bi-1,2,3-triazole-κ2 N3,N 3′)copper(I) hexafluoridophosphate dichloromethane hemisolvate
نویسندگان
چکیده
In the crystal structure of the title compound, [Cu(C(18)H(16)N(6))(C(36)H(28)OP(2))]PF(6)·0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)]PF(6)·0.5CH(2)Cl(2) {DPEPhos = bis-[(diphenyl-phosphan-yl)phen-yl] ether and Bn-bta = 1,1'-dibenzyl-1H,1'H-4,4'-bi-1,2,3triazol-e}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetra-hedral environment. There are two crystallographically independent complex cations present, which differ significantly in their geometrical parameters. The solvent molecule is disordered but satisfactory atomic positions could not be determined.
منابع مشابه
{Bis[2-(diphenylphosphino)phenyl] ether-κ2 P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxylate-κ2 N:N′)copper(I) hexafluoridophosphate acetonitrile solvate
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007